Don't limit yourself to one technique. The Path Tool works well in most situations, but the Fuzzy Select can sometimes be quicker and do a better job with complex edges. Personally, I prefer to use a layermask rather than cutting out selections (painting black the area to be removed) -- this permits easy recovery if I accidentally remove too much (just switch to painting with white).
Also, consider creating a new display (View->New View) and using the Contrast Display Filter to enhance the edges of your render.
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